Unprecedented copper(I)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine.
نویسندگان
چکیده
The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu(2)O and NaN(3) with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 40 21 شماره
صفحات -
تاریخ انتشار 2011